Cover Gallery
73.
金属-金属結合の一次元伸張化: Frontier Orbital Engineering
植村 一広*
submitted for the publication.
72.
3つもしくは5つの金属が並んだ一次元金属オリゴマーの合成
植村 一広*
機能材料, 2025, 45, 10–17. 〔Link〕
71.
Construction of Heterometallic One-Dimensional Chain with δ* in the HOMO
Using Quadruple Hydrogen Bonds
K. Uemura,* T. Yamada
Eur. J. Inorg. Chem., 2025, 28, e202400609.
DOI: 10.1002/ejic.202400609
70.
Structure and Redox Behaviour of a Paramagnetic Rh–Pt–Cu–Pt–Rh Heterometallic-
Extended Metal -Atom Chain
K. Uemura,* Y. Ikeda
Dalton Trans., 2024, 53, 12867–12871.
DOI: 10.1039/D4DT01134A
69.
Enhanced Electrical Conductivity of Polyoxometalates by Bridging with Mixed-valent
Multinuclear Platinum Complexes
K. Uemura,* M. Oshika, H. Hasegawa, A. Takamori, M. Sato
Angew. Chem. Int. Ed., 2024, 63, e202407743.
DOI: 10.1002/anie.202407743 〔Selected as Back Cover〕
68.
Antiferromagnetic Interactions through the Thirteen Å Metal–Metal Distances
in Heterometallic One-dimensional Chains
K. Uemura,* T. Adachi, A. Takamori, M. Yoshida
Angew. Chem. Int. Ed., 2024, 63, e202408415.
DOI: 10.1002/anie.202408415 〔Selected as Frontispiece〕
67.
Binding Ability of Chloride Ion with Platinum and Rhodium Dinuclear Complex
Containing Ethylenediamine as Co-ligand
K. Uemura*
Inorg. Chim. Acta, 2024, 570, 122171.
DOI: 10.1016/j.ica.2024.122171 SSRN
66.
Promotion of ABCG2 gene expression by neolignans from Piper longum L
A. Nishina,* M. Ukiya, K. Motegi, R. Kiryu, D. Sato, M. Sada, Y. Hori,
H. Satsu, K. Uemura, M. Koketsu, M. Ninomiya, L. Myint, H. Kimura
Bioscience, Biotechnology, and Biochemistry, 2023, 87, 1523–1531.
DOI: 10.1093/bbb/zbad132
65.
Structural and Magnetic Properties of Cyclic Tetranuclear or Hexanuclear
Complexes Synthesized with [PtCl2(NCtBu)2] and CuCl2 under Basic Conditions
K. Uemura,* H. Shimofusa
Polyhedron,2023, 243, 116513.
DOI: 10.1016/j.poly.2023.116513
64.
Asymmetrical Platinum and Rhodium Dinuclear Complex Strongly Bound to Filled
dz2 Complexes by Unbridged Pt–metal Bonds Toward Heterometallic-Extended
Metal Atom Chains
K. Uemura,* Y. Ikeda, A. Takamori, T. Takeyamai, S. Iwatsuki
Chem. Eur. J., 2023, 29, e202204057.
DOI: 10.1002/chem.202204057 〔Selected as Inside Cover〕
63.
Recent studies on the magnetic properties of paramagnetic metals linked
by diamagnetic second metals
K. Uemura,* A. Takamori
Coord. Chem. Rev., 2022, 471, 214736.
DOI: 10.1016/j.ccr.2022.214736
62.
Structure and magnetic behavior of a two-dimensional honeycomb sheet containing
trans-bridged platinum and iron trinuclear complex linked using rhodium
acetate with chloride coordination
A. Takamori, K. Uemura*
Polyhedron, 2022, 224, 116017.
DOI: 10.1016/j.poly.2022.116017
61.
Octanuclear heterometallic one-dimensional complex extended by metal–metal
bonds showing MMLCT in the visible region
K. Uemura,* K. Sakurai, Y. Kobayashi
Inorg. Chem. Commun., 2022, 142, 109640.
DOI: 10.1016/j.inoche.2022.109640
60.
Dimerization of paramagnetic trinuclear complexes by coordination geometry
changes showing mixed-valency and significant antiferromagnetic coupling
through –Pt···Pt– bonds
A. Takamori, K. Uemura*
Inorg. Chem., 2022, 61, 5762–5778.
DOI: 10.1021/acs.inorgchem.1c03848 〔Selected as Supplementary Journal Cover〕
59.
Paramagnetic One-dimensional Chain Containing High-spin Manganese Atoms
Showing Weak Antiferromagnetic Interaction Through –Pt–Rh–Rh–Pt–Bonds
K. Uemura,* Y. Aoki, A. Takamori
Dalton Trans., 2022, 51, 946–957.
DOI: 10.1039/D1DT03537A
58.
Crystal Structure of Platinum and Rhodium Discrete Hexanuclear Complex
with Polyethylene Glycol
K. Uemura*
X-Ray Structure Analysis Online, 2022, 38, 25–26.
DOI: 10.2116/xraystruct.38.25
57.
Evidence of electronic interactions between end platinum atoms of hexanuclear
units in heterometallic one-dimensional chains
K. Uemura,* Y. Sugiyama
J. Mol. Str., 2022, 1250, 131694.
DOI: 10.1016/j.molstruc.2021.131694
56.
Improving the Solubility of Hexanuclear Heterometallic Extended Metal Atom
Chain Compounds in Nonpolar Solvents by Introducing Alkyl Amine Moieties
K. Uemura,* E. Yasuda, Y. Sugiyama
ACS Omega, 2021, 6, 18487–18503.
DOI: 10.1021acsomega.1c02634
55.
Modulation of Band Gaps Toward Varying Conductivities in Heterometallic
One-dimensional Chains by Ligand Alteration and Third Metal Insertion
K. Uemura,* D. Ito, J. Pirillo, Y. Hijikata, A. Saeki
ACS Omega, 2020, 5, 30502-30518.
DOI: 10.1021/acsomega.0c04317 〔Selected as Front Cover Picture〕
54.
Paramagnetic One-Dimensional Chain Complex Consisting of Three Kinds of
Metallic Species Showing Magnetic Interaction Through Metal-Metal Bonds
K. Uemura,* R. Miyake
Inorg. Chem., 2020, 59, 1692-1701.
DOI: 10.1021/acs.inorgchem.9b02844 〔Selected as Supplementary Journal Cover〕
53.
Improving Isosteric Heat of CO2 Adsorption by Introducing Nitro Moieties
into Jungle-Gym-Type Porous Coordination Polymers
K. Uemura,* T. Tomida, M. Yoshida
J. Solid State Chem., 2019, 270, 11-18.
DOI: 10.1016/j.jssc.2018.10.039
52.
Magnetic Behavior in Heterometallic One-dimensional Chains or Octanuclear
Complex Regularly Aligned with Metal–Metal Bonds as –Rh–Rh–Pt–Cu–Pt
K. Uemura*
J. Mol. Str., 2018, 1162, 31-36.
DOI: 10.1016/j.molstruc.2018.02.078
51.
Isolation and Characterization of Tetranuclear Pt-Fe---Fe-Pt Intermediate
en Route to the Trinuclear Pt-Fe-Pt Cluster
K. Uemura,* M. Taoka
Dalton Trans., 2017, 46, 14012-14020.
DOI: 10.1039/C7DT02583A
50.
One-dimensional complexes extended by unbridged metal-metal bonds based
on a HOMO-LUMO interaction at the dz2 orbital between platinum and heterometal
atoms
K. Uemura*
Dalton Trans., 2017, 46, 5474-5492.
DOI: 10.1039/C6DT04515D 〔Selected as Back Cover Picture〕
49.
異種金属一次元鎖錯体の常磁性化と磁化率測定
植村 一広*
分子研レターズ, 2017, 75, 33-34. 〔Link〕
48.
異種金属結合による元素ブロック多核錯体の一次元配列
植村 一広*
セラミックス, 2016, 51 (11), 748-751. 〔Link〕
47.
Integration of Paramagnetic Diruthenium Complexes into an Extended Chain
by Heterometallic Metal-Metal Bonds with Diplatinum Complexes
K. Uemura,* N. Uesugi, A. Matsuyama, M. Ebihara, H. Yoshikawa, K. Awaga
Inorg. Chem., 2016, 55, 7003-7011.
DOI: 10.1021/acs.inorgchem.6b00741
46.
Heterometallic one-dimensional chain with tetradeca metal repetition constructed
by amidate bridged dirhodium and pivalate bridged diplatinum complexes
influenced by hydrogen bonding
T. Yamada, M. Ebihara, K. Uemura*
Dalton Trans., 2016, 45, 12322-12328.
DOI: 10.1039/C6DT01601D 〔Selected as Back Cover Picture〕
45.
113Cd Nuclear Magnetic Resonance as a Probe of Structural Dynamics in a Flexible
Porous Framework Showing Selective O2/N2 and CO2/N2 Adsorption
R. Haldar, M. Inukai, S. Horike, K. Uemura, S. Kitagawa, T. K. Maji*
Inorg. Chem., 2016, 55, 4166-4172.
DOI: 10.1021/acs.inorgchem.5b02873
44.
Acetamidate-bridged paddlewheel dirhodium complex sandwiched by mononuclear
platinum complexes with axial metal-metal bonds affording neutral heterometallic
one-dimensional alignments
K. Uemura,* T. Yamada, T. Kanbara, M. Ebihara
Inorg. Chim. Acta, 2015, 424, 194-201.
Special Issue in honor of Professor A. F. Cotton
DOI: 10.1016/j.ica.2014.08.041
43.
Mixed Valency in Quadruple Hydrogen-Bonded Dimers of Bis(biimidazolate)dirhodium
Complexes
J. Long, Y. Matsuda, K. Uemura, M. Ebihara*
Inorg. Chem., 2015, 54, 2331-2338.
DOI: 10.1021/ic502953b
42.
複数種の金属で構成される一次元鎖錯体
植村 一広*
化学と工業, 2014, 67 (7), 622-623. 〔Link〕
41.
Assembled structures of tetrakis(biimidazole)dirhodium complexes hydrogen-bonded
with common inorganic anions
J. Long, K. Uemura, M. Ebihara*
Acta Cryst., 2014, B70, 1006-1019.
DOI: 10.1107/S2052520614021428
40.
Two Types of Heterometallic One-Dimensional Alignment Composed of Acetamidate-Bridged
Dirhodium and Pivalamidate-Bridged Diplatinum Complexes
K. Uemura,* T. Kanbara, M. Ebihara
Inorg. Chem., 2014, 53, 4621-4628.
DOI: 10.1021/ic500305n
39.
Syntheses, crystal structures, and copper-binding capabilities of amidate-hanginsg
platinum mononuclear complexes containing alkylamine moieties
K. Uemura,* Y. Sugiyama, E. Yasuda, M. Ebihara
Polyhedron, 2014, 67, 513-519.
DOI: 10.1016/j.poly.2013.09.037
38.
Paramagnetic One-Dimensional Chains Comprised of Trinuclear Pt-Cu-Pt and
Paddlewheel Dirhodium Complexes with Metal-Metal Bonds
K. Uemura,* M. Ebihara
Inorg. Chem., 2013,52, 5535-5550.
DOI: 10.1021/ic400470g
37.
Crystal Structure of cis-[PtCl2(PyCN)2] (PyCN = 4-Cyanopyridine) Showing Temperature Dependent Single-Crystal-to-Single-Crystal
Transformation
K. Uemura*
Advances in Materials Physics and Chemistry, 2013, 3, 36-40.
DOI: 10.4236/ampc.2013.31A005
36.
Crystal Structures and Adsorption Spectra of Mono-Dimensional Heterometallic
Hexanuclear Complexes with No Bridge Assisted Rhodium-Platinum Bonds
K. Uemura,* K. Sakurai, E. Yasuda, M. Ebihara
Polyhedron, 2012, 45, 35-42.
DOI: 10.1016/j.poly.2012.06.091
35.
One-Dimensionally Extended Paddlewheel Dirhodium Complexes from Metal-Metal
Bonds with Diplatinum Complexes
K. Uemura,* M. Ebihara*
Inorg. Chem., 2011, 50, 7919-7921.
DOI: 10.1021/ic200786k
34.
MOFの合成研究と細孔の特徴 黎明期から成長期の研究例をみて
植村 一広,* 海老原 昌弘
ゼオライト, 2011, 28, 55-64. 〔Link〕
33.
Two-Step Adsorption on Jungle-Gym-Type Porous Coordination Polymers: Dependence
on Hydrogen-Bonding Capability of Adsorbates, Ligand-Substituent Effect,
and Temperature
K. Uemura,* Y. Yamasaki, F. Onishi, H. Kita, M. Ebihara
Inorg. Chem., 2010, 49, 10133-10143.
DOI: 10.1021/ic101517t
32.
Synthesis, Crystal Structure, and Characterization of a Heterometallic
One-Dimensional Complex with Metal-Metal Bonds
K. Uemura,* K. Fukui, K. Yamasaki, K. Matsumoto,* M. Ebihara
Inorg. Chem., 2010, 49, 7323-7330.
DOI: 10.1021/ic1004775
31.
分離
植村 一広*
配位空間の化学 －最新技術と応用－, シーエムシー出版, 2009, 126-134.
30.
Syntheses, crystal structures, and water adsorption behaviors of jungle-gym-type
porous coordination polymers containing nitro moieties
K. Uemura,* F. Onishi, Y. Yamasaki, H. Kita
J. Solid State Chem., 2009, 182, 2852-2857.
DOI: 10.1016/j.jssc.2009.07.048
29.
Syntheses, Crystal Structures, and Adsorption Properties of Ultramicroporous
Coordination Polymers Constructed from Hexafluorosilicate Ions and Pyrazine
K. Uemura,* A. Maeda, T. K. Maji, P. Kanoo, H. Kita
Eur. J. Inorg. Chem., 2009, 2329-2337.
DOI: 10.1002/ejic.200900144 〔Selected as Cover Picture〕
28.
Adsorption and Catalytic Properties of the Inner Nanospace of a Gigantic
Ring-Shaped Polyoxometalate Cluster
S-i. Noro,* R. Tsunashima, Y. Kamiya, K. Uemura, H. Kita, L. Cronin, T. Akutagawa, T. Nakamura*
Angew. Chem. Int. Ed., 2009, 48, 8703-8706.
DOI: 10.1002/anie.200903142
27.
Selective Gas Adsorption in One-Dimensional, Flexible CuII Coordination
Polymers with Polar Units
S-i. Noro,* D. Tanaka, H. Sakamoto, S. Shimomura, S. Kitagawa, S. Takeda,
K. Uemura, H. Kita, T. Akutagawa, T. Nakamura*
Chem. Mater., 2009, 21, 3346-3355.
DOI: 10.1021/cm9012969
26.
Structure and Separation Performance of Carbon Membranes from Lignin-based
Materials
T. Koga, H. Kita,* K. Uemura, K. Tanaka, I. Kawafune, M. Funaoka
Trans. Mater. Res. Soc. Jpn., 2009, 34, 371-374.
DOI: 10.14723/tmrsj.34.371
25.
Characterization of organic solvents adsorption/desorption on hydrophobic
porous coordination polymers and their micro-crystals aggregation on mullite
support
K. Uemura,* Y. Komagawa, Y. Yamasaki, H. Kita
Desalination, 2008, 234, 1-8.
DOI: 10.1016/j.desal.2007.09.063
24.
Zipped-up Chain-type Coordination Polymers: Unsymmetrical Amide-Containing
Ligands Inducing β-Sheet or Helical Structures
K. Uemura,* Y. Kumamoto, S. Kitagawa
Chem. Eur. J., 2008, 14, 9565-9576.
DOI: 10.1002/chem.200800806
23.
Syntheses and Crystal Structures of Straight or Zigzag One-dimensional
Coordination Polymers Based on Cu(II) Square Pyramidal or Cu(I) Tetrahedral
Coordination Environments
K. Uemura,* A. Maeda, H. Kita
Polyhedron, 2008, 27, 2939-2942.
DOI: 10.1016/j.poly.2008.06.030
22.
Syntheses and crystal structures of novel silver(I) coordination polymers
based on linear or tetrahedral coordination environments
K. Uemura*
Inorg. Chem. Commun., 2008, 11, 741-744.
DOI: 10.1016/j.inoche.2008.03.026
21.
Temperature- and Stoichiometry-Controlled Dimensionality in a Magnesium
4,5-Imidazoledicarboxylate System with Strong Hydrophilic Pore Surfaces
K. L. Gurunatha, K. Uemura, T. K. Maji*
Inorg. Chem., 2008, 47, 6578-6580.
DOI: 10.1021/ic8007377
20.
Carbon membranes from wood materials and their separation properties
T. Koga, H. Kita,* T. Suzuki, K. Uemura, K. Tanaka, I. Kawafune, M. Funaoka
Trans. Mater. Res. Soc. Jpn., 2008, 33, 825-828.
19.
Stepwise Alcohol Adsorption on a Jungle-Gym-Analog Hydrophobic Porous Coordination
Polymer
K. Uemura,* Y. Yamasaki, Y. Komagawa, K. Tanaka, H. Kita
The 4th Conference of Aseanian Membrane Society (Proceedngs), 2007, 201-202.
18.
ナノポーラス金属錯体の材料合成と機能展開
北川 進,* 植村 一広
有機貯蔵材料とナノ技術 －水素社会に向けて－, シーエムシー出版, 2007, 243-257.
17.
Two-Step Adsorption/Desorption on a Jungle-Gym-Type Porous Coordination
Polymer
K. Uemura,* Y. Yamasaki, Y. Komagawa, K. Tanaka, H. Kita
Angew. Chem. Int. Ed., 2007, 46, 6662-6665.
DOI: 10.1002/anie.200702390
16.
Synthesis of Amidate-Hanging Platinum Mononuclear Complexes by Base Hydrolysis
of Nitriles Complexes
K. Uemura, K. Yamasaki, K. Fukui, K. Matsumoto*
Inorg. Chim. Acta, 2007, 360, 2623-2630.
DOI: 10.1016/j.ica.2006.12.036
15.
Synthesis, Crystal Structures, and Oxidation States of MM'X-type Platinum-Rhodium
Dinuclear Complexes Having Amidate Bridging Ligands
K. Uemura, K. Yamasaki, K. Fukui, K. Matsumoto*
Eur. J. Inorg. Chem., 2007, 809-815.
DOI: 10.1002/ejic.200600902
14.
白金-ロジウム混合原子価多核錯体の合成と一次元集積化
植村 一広*
Bull. Jpn. Soc. Coord. Chem., 2006, 47, 22-23.
13.
Hydrogen-Bonded Porous Coordination Polymers: Structural Transformation,
Sorption Properties, and Particle Size from Kinetic Studies
K. Uemura,* K. Saito, S. Kitagawa, H. Kita
J. Am. Chem. Soc., 2006, 128, 16122-16130.
DOI: 10.1021/ja064152r
12.
A Paramagnetic Quasi-1D Chain Comprised of Pt/Rh Possessing an Unpaired
Electron
K. Uemura, K. Fukui, K. Yamasaki, K. Matsumoto*
Sci. Technol. Adv. Mater., 2006, 7, 461-467.
DOI: 10.1016/j.stam.2006.05.006
11.
Isomerization Reaction of Head-to-Head α-Pyridonato-Bridged Ethylenediaminepalladium(II) Binuclear Complex, [Pd2(en)2(C5H4NO)2]2+, in Aqueous Solution
S. Iwatsuki,* T. Itou, H. Ito, H. Mori, K. Uemura, Y. Yokomori, K. Ishihara,* K. Matsumoto*
Dalton Trans., 2006, 1497-1504.
DOI: 10.1039/b515743a 〔Selected as Inside Cover Picture〕
10.
配位高分子結晶ナノ空間の未踏機能
北川 進,* 植村 一広
高分子, 2005, 54 (2), 63-66.
DOI: 10.1295/kobunshi.54.63
9.
Flexible Microporous Coordination Polymers
K. Uemura, R. Matsuda, S. Kitagawa*
J. Solid State Chem., 2005, 178, 2420-2429.
DOI: 10.1016/j.jssc.2005.05.036
8.
Paramagnetic Platinum-Rhodium Octamers Bridged by Halogen Ions To Afford
a Quasi-1D System
K. Uemura, K. Fukui, H. Nishikawa, S. Arai, K. Matsumoto,* H. Oshio
Angew. Chem. Int. Ed., 2005, 44, 5459-5464.
DOI: 10.1002/anie.200501049
7.
Thermodynamic Aspect of Reversible Structural Conversion Induced by Guest
Adsorption/Desorption Based on Infinite Co(NCS)2Py4 (Py = pyridine) System
K. Uemura,* S. Kitagawa, K. Saito, K. Fukui, K. Matsumoto
J. Therm. Anal. Calorim., 2005, 81, 529-532.
DOI: 10.1007/s10973-005-0816-1
6.
Dynamic Porous Properties of Coordination Polymers Inspired by Hydrogen
Bonds
S. Kitagawa,* K. Uemura
Chem. Soc. Rev., 2005, 34, 109-119.
DOI: 10.1039/b313997m
5.
Expanding and Shrinking Porous Modulation Based on Pillared-Layer Coordination
Polymers Showing Selective Guest Adsorption
T. K. Maji, K. Uemura, H-C. Chang, R. Matsuda, S. Kitagawa*
Angew. Chem. Int. Ed., 2004, 43, 3269-3272.
DOI: 10.1002/anie.200453923 〔Selected as Cover Picture〕
4.
A Contrivance for a Dynamic Porous Framework: Cooperative Guest Adsorption
Based on Square Grids Connected by Amide-Amide Hydrogen Bonds
K. Uemura, S. Kitagawa,* K. Fukui, K. Saito
J. Am. Chem. Soc., 2004, 126, 3817-3828.
DOI: 10.1021/ja039914m
3.
ナノ細孔をもつ新しい金属錯体材料
植村 一広, 北川 進*
未来材料, 2002, 2 (12), 44-51. 〔Link〕
2.
Novel Flexible Frameworks of Porous Cobalt(II) Coordination Polymers That
Show Selective Guest Adsorption Based on the Switching of Hydrogen-Bond
Pairs of Amide Groups
K. Uemura, S. Kitagawa,* M. Kondo, K. Fukui, R. Kitaura, H-C. Chang, T. Mizutani
Chem. Eur. J., 2002, 8, 3586-3600.
DOI: 10.1002/1521-3765(20020816)8:16<3586::AID-CHEM3586>3.0.CO;2-K
〔Selected as Frontispiece Picture〕
