工学部 化学・生命工学科 安藤研究室  

   

研究業績

Go to Prof. Oka's list of publications

安藤 香織

  1. 安藤香織[著]「アルケンの合成」(化学の要点シリーズ27, 日本化学会[編], 共立出版)

  2. Oka, N.; Mori, A.; Ando, K. "Stereoselective synthesis of 1-thio-α-D-ribofuranosides using ribofuranosyl iodides as glycosyl donors" Eur. J. Org. Chem. 2018, in press.

  3. Ando, K.; Takao, M.; Oyama, I.; Furuta, K. "One-pot preparation of ethyl 2(Z)-4-(anilinoxy)pentenoate by α-aminoxylation of propanal followed by Z-selective HWE reaction and the study on its cyclization reaction" Heterocycles 2018, 96, 15931600.

  4. Oka, N.; Fukuta, A.; Ando, K. "A practical synthesis of archaeosine and its base" Tetrahedron 2018, 74, 57095714.

  5. Ando, K. "Methylenation Reaction of Carbonyl Compounds Using Julia-Kocienski Reagents" p. 147-162. in "New Horizons of Process Chemistry" Edited by Kiyoshi Tomioka, Takayuki Shioiri, and Hironao Sajiki, Springer, Nature Singapore Pte Ltd. 2017.

  6. Oka, N.; Ori, K.; Ando, K. Synthesis of 2-pyridylthiophosphinic acids and 2-pyridylthiophosphonate monoesters via nucleophilic aromatic substitution. Phosphorus, Sulfur Silicon Relat. Elem. 2017, 192, 454463.

  7. Ando, K.; Wada, T.; Okumura, M.; Sumida, H. Stereoselective synthesis of Z-α,β-unsaturated sulfones using Peterson reagents. Org. Lett. 2015, 17, 60266029.

  8. Bayliffe, F. H.; Steven, A.; Ando, K.; Shipman, M. Sodium amide induced cyclization of 2-iodoprop-2-enylamines: application to the synthesis of 1-aryl-2-methyleneaziridines. Synlett 2015, 26, 13711374.

  9. Ando, K.; Kobayashi, T.; Uchida, N. Practical methylenation reaction for aldehydes and ketones using new Julia-type reagents. Org. Lett. 2015, 17, 25542557.

  10. 安藤香織「理論計算の有機合成への活用」有機合成化学協会誌 2014, 72, 891-898 and 943.

  11. Oka, N.; Kajino, R.; Takeuchi, K.; Nagakawa, H.; Ando, K. α-Selective ribofuranosylation of alcohols with ribofuranosyl iodides and triphenylphosphine oxide. J. Org. Chem. 2014, 79, 76567664.

  12. Oka, N.; Morita, Y.; Itakura, Y.; Ando, K. Synthesis of inosine 6-phosphate diesters via phosphitylation of carbonyl oxygen. Chem. Commun. 2013, 49, 1150311505.

  13. Ando, K.; Okumura, M.; Nagaya, S. Highly Z-selective synthesis of α,β-unsaturated nitriles using the Horner-Wadsworth-Emmons reaction.  Tetrahedron Lett. 2013, 54, 20262028.

  14. Nomura, Y.; Onda, Y.; Ohno, S.; Taniguchi, H.; Ando, K.; Oka, N.; Nishikawa, K.; Yokogawa, T. Purification and comparison of native and recombinant tRNA-guanine transglycosylases from Methanosarcina acetivorans. Protein Expr. Purif. 2013, 88, 1319.

  15. Oka, N.; Ito, K.; Tomita, F.; Ando, K. Synthesis of 2-pyridylphosphinate and thiophosphinate derivatives by nucleophilic aromatic substitution of N-methoxypyridinium tosylates. Chem. Lett. 2012, 41, 16301632.

  16. Oka, N.; Takayama, Y.; Ando, K.; Wada, T. Synthesis of nucleoside 5'-boranophosphorothioate derivatives using an H-boranophosphonate monoester as a precursor. Bioorg. Med. Chem. Lett. 2012, 22, 45714574.

  17. Goto, T.; Takeda, K.; Anada, M.; Ando, K.; Hashimoto, S. Enantio- and diastereoselective cyclopropanation with tert-butyl a-diazopropionate catalyzed by dirhodium(II) tetrakis[N-tetrabromophthaloyl-(S)-tert-leucinate]. Tetrahedron Lett. 2011, 52, 42004203.

  18. Ando, K.; Morokuma, K. DFT and ONIOM study on the alkylation of the lithium enolate in solution: microsolvation cluster models for CH2=CHOLi + CH3Cl + (THF)06. Theo. Chem. Acc. 2011, 130, 323331.

  19. Goto, T.; Takeda, K.; Shimada, N.; Nambu, H.; Anada, M.; Shiro, M.; Ando, K.; Hashimoto, S. Highly enantioselective cyclopropenation reaction of 1-alkynes with a-alkyl-a-diazoesters catalyzed by dirhodium(II) carboxylates. Angew. Chem. Int. Ed. 2011, 50, 68036808.

  20. Ando, K.; Yamada, K. Highly E-selective solvent-free Horner-Wadsworth-Emmons reaction catalyzed by DBU. Green Chem. 2011, 13, 11431146.

  21. 安藤香織 「使える!有機合成反応241実践ガイド」(丸岡ら編)(化学同人)「Z選択的Horner-Wadsworth-Emmons反応を活用するZ-a,b-不飽和アミドの合成」2010, pp. 136137.

  22. 安藤香織 「使える!有機合成反応241実践ガイド」(丸岡ら編)(化学同人)「Z選択的Horner-Wadsworth-Emmons反応を活用するZ-a,b-不飽和ラクトンの合成」2010, pp. 138139.

  23. 安藤香織 「使える!有機合成反応241実践ガイド」(丸岡ら編)(化学同人)「高E選択的無溶媒Horner-Wadsworth-Emmons反応」2010, pp. 140141.

  24. Yamanichi, H.; Matsukawa, S.; Kojima, S.; Ando, K.; Yamamoto, Y. Structure and dynamic behavior of neutral hexacoordinate antimony compounds with intramolecular coordination. Heteroatom Chem. 2011, 22, 553561.

  25. Ando, K.; Sato, K. Z-Selective intramolecular Horner-Wadsworth-Emmons reaction for the synthesis of macrocyclic alkenes. Tetrahedron Lett. 2011, 52, 12841287.

  26. Ando, K. Mechanistic study on the gold-catalyzed C-S bond formation of a-thioallenes to form 2,5-dihydrothiophenes. J. Org. Chem. 2010, 75, 85168521. E-print for non-subscriber (Please log in with your ACS ID.)

  27. Ando, K.; Egami, T. Facile synthesis of a-amino phosphonates in water by Kabachnik-Fields reaction using magnesium dodecyl sulfate. Heteroatom Chem. 2011, 22, 358362.

  28. Ando, K.; Yamada, K. Solvent-free Horner-Wadsworth-Emmons reaction using DBU. Tetrahedron Lett. 2010, 51, 32973299.

  29. Ando, K.; Narumiya, K.; Takada, H.; Teruya, T. Z-Selective intramolecular Horner-Wadsworth-Emmons reaction for the synthesis of macrocyclic lactones. Org. Lett. 2010, 12, 14601463.[Highlighted in Organic Chemistry Highlights 2010]

  30. Ando, K.; Suzuki, Y. New polymer-supported phosphonate reagents for the synthesis of Z-α,β-unsaturated esters. Tetrahedron Lett. 2010, 51, 23232325. [Highlighted in Synfacts 2010, 6, 722.]

  31. Matsukawa, S.; Yamamichi, H.; Yamamoto, Y.; Ando, K. Pentacoordinate Organoantimony compounds that isomerizes by turnstile rotation. J. Am. Chem. Soc. 2009, 131, 34183419.

  32. Chiba, S.; Ando, K.; Narasaka, K. Concerted nucleophilic substitution reactions at vinylic carbons. Synlett 2009, 25492564.

  33. Lei, M.-Y.; Xiao, Y.-J.; Liu, W.-M.; Fukamizu, K.; Chiba, S.; Ando, K.; Narasaka, K. Nucleophilic substitution reaction at an sp2 carbon of vinyl halides with an intramolecular thiol moiety: synthesis of thio-heterocycles. Tetrahedron 2009, 65, 68886902.

  34. Ando, K.; Nagaya, S.; Tarumi, Y. Bis(2-t-butylphenyl)phosphonoacetamides for the highly cis-selective synthesis of a,b-unsaturated amides. Tetrahedron Lett. 2009, 50, 56895691.

  35. 安藤香織 「私の『薬学研究への道』」「薬奨ニュース」,2009年6月No.9, 8.

  36. Lei, M.-Y.; Fukamizu, K.; Xiao, Y.-J.; Liu, W.-M.; Twiddy, S.; Chiba, S.; Ando, K.; Narasaka, K. Nucelophilic substitution at an sp2 carbon of vinyl halides with an intramolecular thiolate moieties: synthesis of 2-alkylidenethietanes. Tetrahedron Lett. 2008, 49, 4125–4129.

  37. Seio, K.; Sasami, T.; Ohkubo, A.; Ando, K.; Sekine, M. Highly selective recognition of cytosine over urasil and adenine by a guanine analog, 2-N-acetyl-3-deazaguanine, in 2¢-O-methyl-RNA/RNA duplexes. J. Am. Chem. Soc. 2007, 129, 10261027.

  38. Miyauchi, H.; Chiba, S.; Ando, K.; Narasaka, K. Synthesis of hetero- and carbocycles by nucleophilic substitution at sp2 carbon. Tetrahedron 2007, 63, 59405953.

  39. Saneyoshi, H.; Ando, K.; Seio, K.; Sekine, M. New aspects of the cyanoethyl group at the smallest-sized protecting group of the 2¢-hydroxyl function capable of smooth condensation and easy protection-deprotection under mild conditions in the chemical synthesis of RNA. Tetrahedron 2007, 63, 1119511203.

  40. 安藤香織 「選択的Horner-Wadsworth-Emmons試薬の開発秘話」 TCIメール 2007, 135, 1213.

  41. Ando, K. Theoretical study on the lithium-halogen exchange reaction of 1,1-dihaloalkenes with methyllithium and the nucleophilic substitution reaction of the resulting a-halo alkenyllithiums. J. Org. Chem. 2006, 71, 18371850.

  42. Ando, K. A theoretical study on the origin of p-facial stereoselectivity in the alkylation of enolates derived from 4-substituted g-butyrolactones. J. Am. Chem. Soc. 2005, 127, 3964–3972.

  43. Sato, T.; Ogino, Y.; Ando, K. Direct alkenylation of arylamines at the ortho-position with magnesium alkylidene carbenoids and some theoretical studies of the reactions. Tetrahedron 2005, 61, 10262–10276.

  44. Ando, K.; Kitamura, M.; Miura, K.; Narasaka, K. Theoretical and experimental study on the in-plane SN2 type substitution reaction of haloalkenes with inversion of configuration at vinylic carbon. Org. Lett. 2004, 6, 24612463.

  45. Ando, K. Theoretical study of the nucleophilic 5-endo-trigonal cyclization of 1,1,-difluoro-1-alkenes. J. Org. Chem. 2004, 69, 4204–4209.

  46. 安藤香織 「理論計算から始まる有機合成への挑戦」 日本化学会誌「化学と工業」57巻、931932 (2004).

  47. Yanagisawa, H.; Miura, K.; Kitamura, M.; Narasaka, K.; Ando, K. Intramolecular substitution reaction of lithium alkylidene carbenoids; regioselective synthesis of indenes. Bull. Chem. Soc. Jp. 2003, 76, 2009–2026.

  48. Yanagisawa, H.; Miura, K.; Kitamura, M.; Narasaka, K.; K. Ando. Intramolecular substitution reaction of alkylidene-lithium carbenoids: Regioselective synthesis of indenes. Helv. Chim. Acta 2002, 85, 3130–3135.

  49. Ohno, H.; Ando, K.; Hamaguchi, H.; Takeda, Y.; Tanaka, T. A highly cis-selective synthesis of 2-ethynylaziridines by intramolecular amination of chiral bromoallenes: Improvement of stereoselectivity based on the computational investigation. J. Am. Chem. Soc. 2002, 124, 15255–15266.

  50. 安藤香織 'Z-Selective Horner-Wadsworth-Emmons Reaction' 有機合成化学協会60周年記念出版『My Favorite Organic Synthesis』(野依良治編)2002年7月出版、p.67. 『有機合成 創造の軌跡 126のマイルストーン』My Favorite Organic(非売品)の市販品、化学同人

  51. 安藤香織 ホルナ・エモンズ反応の反応機構の解明と立体選択的α,β-不飽和エステル類合成への応用 薬学研究の進歩, 1523 (2001).

  52. Ando, K. Preparations of Z-a,b-unsaturated amides by using Horner-Wadsworth-Emmons reagents, (diphenylphosphono)acetamides. Synlett 2001, 1272–1274.

  53. 安藤香織 選択的Horner-Wadsworth-Emmons試薬の開発 有機合成化学協会誌、2001595号、418419.特集号:今、若手研究者はなにを目指しているか)

  54. Ando, K.; Oishi, T.; Hirama, M.; Ohno, H.; Ibuka, T. Z-Selective Horner-Wadsworth-Emmons reaction of ethyl (diarylphosphono)acetates using sodium iodide and DBU. J. Org. Chem. 2000, 65, 4745–4749.

  55. Behnam, S. M.; Behnam, S. E.; Ando, K.; Green, N. S.; Houk, K. N. Stereoelectronic, torsional, and steric effects on rates of enolization of ketones. J. Org. Chem. 2000, 65, 8970–8978.

  56. 安藤香織 Z-選択的Horner-Wadsworth-Emmons反応 有機合成化学協会誌、第58巻、8698762000年).

  57. Ando, K.; Green, N. S.; Li, Y.; Houk, K. N. Torsional and steric effects control the stereoselectivities of alkylations of pyrrolidinone enolates. J. Am. Chem. Soc. 1999, 121, 5334–5335.

  58. Ando, K. A mechanistic study of the Horner-Wadsworth-Emmons reaction: Computational investigation on the reaction pass and the stereochemistry in the reaction of lithium enolate derived from trimethyl phosphonoacetate with acetaldehyde. J. Org. Chem. 1999, 64, 6815–6821.

  59. Ando, K. Convenient preparations of (diphenylphosphono)acetic acid esters and the comparison of the Z-selectivities of their Horner-Wadsworth-Emmons reaction with aldehydes depending on the ester moiety. J. Org. Chem. 1999, 64, 8406–8408.

  60. Ando, K.; Houk, K. N.; Busch, J.; Menasse, A.; Sequin, U. Experimental and computational studies of nucleophilic additions of metal hydrides and organometallics to hindered cyclohexanones. J. Org. Chem. 1998, 63, 1761–1766.

  61. Ando, K.; Condroski, K. R.; Houk, K. N.; Wu, Y.-D.; Ly, S. K.; Overman, L. E. Stereoselectivities of nucleophilic additions to cycloheptanones. Experimental and theoretical studies and general purpose force field for the prediction of nucleophilic addition stereoselectivities. J. Org. Chem. 1998, 63, 3196–3203.

  62. Ando, K. Z-Selective Horner-Wadsworth-Emmons reaction of a-substituted ethyl (diarylphosphono)acetates with aldehydes. J. Org. Chem. 1998, 63, 8411–8416.

  63. Ando, K. Highly selective synthesis of Z-unsaturated esters by using new Horner-Emmons reagents, ethyl diarylphosphonoacetates. J. Org. Chem. 1997, 62, 1934–1939.

  64. Winkler, J. D.; Kim, H. S.; Kim, S.; Ando, K.; Houk, K. N. Stereoselective synthesis of the taxane ring system via the tandem Diels-Alder cycloaddition. J. Org. Chem. 1997, 62, 2957–2962.

  65. Ando, K.; Kankake, M.; Suzuki, T.; Takayama, H. New building blocks, 3,5-dihydro-1H-thieno[3,4-c]pyrrole 2,2-dioxides; Preparation and their Diels-Alder reaction with dimethyl acetylenedicarboxylate. Tetrahedron 1995, 51, 129–138.

  66. Ando, K.; Koike, F.; Kondo, F.; Takayama, H. An improved synthesis of 24,24-difluoro-1a,25-dihydroxyvitamin D3 from readily available vitamin D2. Chem. Pharm. Bull. 1995, 43, 189–192.

  67. Ando, K. Practical synthesis of Z-unsaturated esters by using a new Horner-Emmons reagent, ethyl diphenylphosphonoacetate. Tetrahedron Lett. 1995, 36, 4105–4108.

  68. Ando, K.; Yasuda, K.; Tomioka, K.; Koga, K. Stereoselective reactions. XXIII. Asymmetric Michael reaction of a-alkyl b-keto esters via chiral enamines. Dependence of the diastereoface selection on the combination of solvents and additives. J. Chem. Soc., Perkin Trans. 1 1994, 277–282.

  69. Ando, K.; Kankake, M.; Suzuki, T.; Takayama, H. Diels-Alder reaction of 3,5-dihydro-1H-thieno[3,4-c]pyrrole 2,2-dioxides with alkene dienophiles; Facile preparation of 4,5,6,7-tetrahydroisoindoles. Synlett 1994, 741–742.

  70. Ando, K.; Seo, W.; Tomioka, K.; Koga, K. Stereoselective reactions. XXIV. Chlorotrimethylsilane promoted asymmetric Michael reaction of chiral lithioenamines derived from a-alkyl b-keto esters. Tetrahedron 1994, 50, 13081–13088.

  71. 安藤香織 P-キラルホスフィン、ジホスフィンの実用的合成 日本薬学会誌「ファルマシア」1994308号、906907.

  72. Ando, K.; Takayama, H. Heteroaromatic-fused 3-sulfolenes. Heterocycles 1994, 37, 1417–1439.

  73. Ando, K.; Takemasa, Y.; Tomioka, K.; Koga, K. Stereoselective reactions. XXI. Asymmetric alkylation of a-alkyl b-keto esters to a,a-dialkyl b-keto esters having either (R)- or (S)-chiral quaternary center depending on the solvent system. Tetrahedron 1993, 49, 1579–1588.

  74. Ando, K.; Akadegawa, N.; Takayama, H. Alkylation of 4H,6H-thieno[3,4-c]furan 5,5-dioxide and its use as a 3,4-dimethylenefuran synthon in intramolecular Diels-Alder reaction. J. Chem. Soc., Perkin Trans. 1 1993, 2263–2268.

  75. Ando, K.; Hatano, C.; Akadegawa, N.; Shigihara, A.; Takayama, H. Novel formation of dienes greater steric congestion resulting from the Diels-Alder reaction-desulfonylation sequence of 4-acyl-4H,6H-thieno[3,4-c]furan 5,5-dioxides. J. Chem. Soc., Chem. Commun. 1992, 870–873.

  76. Ando, K.; Kankake, M.; Suzuki, T.; Takayama, H. New building blocks, 3,5-dihydro-1H-thieno[3,4-c]pyrrole 2,2-dioxides; Preparation and their Diels-Alder reaction with dimethyl acetylenedicarboxylate. J. Chem. Soc., Chem. Commun. 1992, 1100–1102.

  77. Ando, K.; Kondo, F.; Koike, F.; Takayama, H. An improved synthesis of 24,24-difluoro-1a,25-dihydroxyvitamin D3 from vitamin D2. Chem. Pharm. Bull. 1992, 40, 1662–1664.

  78. Ando, K.; Akadegawa, N.; Takayama, H. Alkylation of 4H,6H-thieno[3,4-c]furan-5,5-dioxide and its use as a 3,4-dimethylenefuran synthon in intramolecular Diels-Alder reactions. J. Chem. Soc., Chem. Commun. 1991, 1765–1767.

  79. Roush, W. R.; Ando, K.; Powers, D. B.; Palkowitz, A. D.; Halterman, R. L. Asymmetric synthesis using diisopropyl tartrate modified (E)- and (Z)-crotylboronates: Preparation of the chiral crotylboronates and reactions with achiral aldehydes. J. Am. Chem. Soc. 1990, 112, 6339–6348.

  80. Roush, W. R.; Palkowitz, A. D.; Ando, K. Acyclic diastereoselective synthesis using tartrate ester modified crotylboronates. Double asymmetric reactions with a-methyl chiral aldehydes and synthesis of the C(19)-C(29) Segment of Rifamycin S. J. Am. Chem. Soc. 1990, 112, 6348–6359.

  81. 安藤香織、高山浩明 最近のビタミンD誘導体の合成研究 有機合成化学協会誌、第48巻、10821091 (1990).

  82. Roush, W. R.; Ando, K.; Powers, D. B.; Halterman, R. L.; Palkowitz, A. D. Enantioselective synthesis using diisopropyl tartrate modified (E)- and (Z)-crotyl-boronates: Reactions with achiral aldehydes. Tetrahedron Lett. 1988, 29, 5579–5582.

  83. Tomioka, K.; Soe, W.; Ando, K.; Koga, K.        Chlorotrimethylsilane promoted asymmetric Michael reaction of chiral enamines of a-alkyl b-keto esters. Tetrahedron Lett. 1987, 28, 6637–6640.

  84. Tomioka, K.; Ando, K.; Yasuda, K.; Koga, K. Asymmetric Michael reaction of a-alkyl b-keto esters via chiral enamines. Tetrahedron Lett. 1986, 27, 715–716.

  85. Yoshifuji, M.; Toyota, K.; Ando, K.; Inamoto, N. Isolation and characterization of a stable dithioxophorane. Chem. Lett. 1984, 317–318.

  86. Yoshifuji, M.; Shibayama, K.; Ando, K.; Inamoto, N. Isolation and characterization of a thiadiphosphirane. Heterocycles 1984, 21, 475.

  87. Tomioka, K.; Ando, K.; Takemasa, Y.; Koga, K. Factors controlling the diastereoface selectivity in the complementary asymmetric alkylation of a-alkyl b-keto esters. Tetrahedron Lett. 1984, 25, 5677–5680.

  88. Tomioka, K.; Ando, K.; Takemasa, Y.; Koga, K. Asymmetric alkylation of a-alkyl b-keto esters J. Am. Chem. Soc. 1984, 106, 2718–2719.

  89. 安藤香織 光学活性βジカルボニル化合物の合成-キラルアミドエノレートを用いた不斉アシル化反応 日本化学会誌「化学と工業」1984378号、570571.

  90. Yoshifuji, M.; Ando, K.; Shibayama, K.; Inamoto, N.; Hirotsu, K.; Higuchi, T. The first X-ray structure analysis of a thiadiphosphirane. Angew. Chem. Int. Ed. Engl. 1983, 22, 418–419.

  91. Yoshifuji, M.; Ando, K.; Toyota, K.; Inamoto, N. Oxidation of a diphosphene and dechlorination of an arylphosphonic dichloride: Isolation of the diphosphene oxide. J. Chem. Soc., Chem. Commun. 1983, 419–420.

  92. Yoshifuji, M.; Shima, I.; Ando, K.; Inamoto, N. Thermal reactions of (2,4,6-tri-tert-butylphenyl)phosphonous dichloride and its derivatives: Formation of 2,3-dihydro-1H-phosphindoles.              Tetrahedron Lett. 1983, 24, 933–936.