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Curriculum Vitae

Dr. Fumitoshi Shibahara was born in Nara, Japan on July 17, 1974. He received a B.S. degree in industrial chemistry in 1997 from Doshisha University. He joined Professor Tamejiro Hiyama's group at Kyoto University as a Doctor course student in 1997. He obtained his Ph.D. in organic chemistry from Kyoto University in 2003 under the guidance of Professor Kyoko Nozaki (She moved to the University of Tokyo in 2002.) and the supervision of Professor Hiyama. During this period, he worked as a research fellow in Professor Nozaki group attached to JST for two and a half years from Octorber 2000. In April 2003, he joined Professor Toshiaki Murai's group at Gifu University as an assistant professor. During this period, he visited Professor Michael J. Keische's group at University of Texas at Austin as Donald D. Harrington Faculty Fellow from September 2008 to August 2009.

His research interests are 1)Organic synthesis, 2)Asymmetric synthesis, and 3)Catalytic transformation of the bulk materials to the fine chemicals.

e-mail : fshiba:gifu-u.ac.jp (please change : to @)

Publications

Papers

21."Synthesis of Fluorescent 1,3-Diarylated Imidazo[1,5-a]pyridines: Oxidative Condensation|Cyclization of Aryl-2-Pyridylmethylamines and Aldehydes Using Elemental Sulfur as an Oxidant"
Shiibahara, F.; Sugiura, R.; Kitagawa, A.; Yamaguchi, E.; Murai, T. J. Org. Chem. 2009, in press http://dx.doi.org/10.1021/jo900415y

20."Synthesis of 1,3-Diarylated Imidazo[1,5-a]pyridines with a Combinatorial Approach: Metal-catalyzed Cross-coupling Reactions of 1-Halo-3-aryl-imidazo[1,5-a]pyridines with Arylmetal Reagents"
Shiibahara, F.; Yamaguchi, E.; Kitagawa, A.; Imai, A.; Murai, T. Tetrahedron 2009, in press http://dx.doi.org/10.1016/j.tet.2009.02.062

19."Diene Hydroacylation from the Alcohol or Aldehyde Oxidation Level via Ruthenium-Catalyzed C-C Bond-Forming Transfer Hydrogenation: Synthesis of ƒĄ,ƒĮ-Unsaturated Ketones"
Shibahara, F.; Bower, J. F.; Krische, M. J. J. Am. Chem. Soc. 2008, 130, 14120|14122. http://dx.doi.org/10.1021/ja805356j

18."Ruthenium-Catalyzed C|C Bond Forming Transfer Hydrogenation: Carbonyl Allylation from the Alcohol or Aldehyde Oxidation Level Employing Acyclic 1,3-Dienes as Surrogates to Preformed Allyl Metal Reagents"
Shibahara, F.; Bower, J. F.; Krische, M. J. J. Am. Chem. Soc. 2008, 130, 6338-6339.
http://dx.doi.org/10.1021/ja801213x
Highlighted in C&E News 2008, 86(19), 10: http://pubs.acs.org/cen/news/86/i19/8619notw4.html
Highlighted in Synfact 2008, 8, 0831: http://dx.doi.org/10.1055/s-2008.1077906

17."Copper-catalyzed Oxidative Desulfurization-promoted Intramolecular Cyclization of Thioamides Using Molecular Oxygen as an Oxidant: An Efficient Route to Five- to Seven-membered Nitrogen-containing Heterocycles"
Shibahara, F.; Yoshida, A.; Murai, T. Chem. Lett. 2008, 37, 646-647.
http://dx.doi.org/10.1246/cl.2008.646

16."Synthesis of 1,1'-Binaphthyl-2,2'-diyl Phosphoroselenoic Ammonium Salts and their Conversion to Optically Active Dialkyl Diselenides"
Murai. T.; Monzaki, M.; Shibahara, F. Chem. Lett. 2007, 36, 852-853.
http://dx.doi.org/10.1246/cl.2007.852

15."Copper-catalyzed oxidative desulfurization|oxygenation of thiocarbonyl compounds using molecular oxygen: an efficient method for the preparation of oxygen isotopically labeled carbonyl compounds"
Shibahara, F.
; Suenami, A.; Yoshida, A.; Murai, T. Chem. Commun. 2007, 2354-2356.
http://dx.doi.org/10.1039/b701048f

14."Synthesis of 1,1'-Binaphthyl-2,2'-diyl Phosphoroselenoic Amides and Their Conversion to Optically Pure Phosphoramidites"
Murai, T.; Inaji, S.; Morishita, K. Shibahara, F.; Tokunaga, M.; Obora, Y.; Tsuji, Y. Chem. Lett. 2006, 35, 1424-1425.
http://dx.doi.org/10.1246/cl.2006.1424

13."Synthesis of 2-Azaindolizines by Using an Iodine-Mediated Oxidative Desulfurization Promoted Cyclization of N-2-pyridylmethyl Thioamides and an Investigation of Their Photophysical Propaerties"
Shibahara, F.; Kitagawa. A.; Yamaguchi, E.; Murai, T. Org. Lett. 2006, 24, 5621-5624.
http://dx.doi.org/10.1021/ol0623623

12."N-Thioacyl 1,3-Amino Alcohols: Synthesis via Ring-Opening of Oxiranes with Thioamide Dianions and Applications as Key Intermediates Leading to Stereochemically Defined 5,6-Dihydro-4H-1,3-oxazines and 1,3-Amino Alcohols"
Murai, T.; Sano, H.; Kawai, H.; Aso, H.; Shibahara, F. J. Org. Chem. 2005, 70, 8148-8153.
http://dx.doi.org/10.1021/jo051378o

11."Comparison of two preparative methods: a polymer-supported catalyst by metal-complexation with a polymeric ligand or by polymerization of a metal complex"
Kinoshita, S.; Shibahara, F.; Nozaki, K. Green Chem. 2005, 7, 256-258.
http://dx.doi.org/10.1039/b418264b

10."Palladium(II)-Catalyzed Sequential Hydroxylation-Carboxylation of Biphenyl Using Formic Acid as a Carbonyl Source"
Shibahara. F.; Kinoshita, S.; Nozaki, K. Org. Lett. 2004, 6, 2437-2439.
http://dx.doi.org/10.1021/ol049166l

9."Iodo-cyclization of N-Homoallyl Thioamides Leading to 2,4-Diaryl-5,6-dihydro-4H-1,3-thiazines"
Murai, T.; Niwa, H.; Kimura, T.; Shibahara, F.
Chem. Lett.
2004, 33, 508-509.
http://dx.doi.org/10.1246/cl.2004.508

8."Solvent-Free Asymmetric Olefin Hydroformylation Catalyzed by Highly Crosslinked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complex"
Shibahara, F.
; Nozaki, K.; Hiyama, T. J. Am. Chem. Soc. 2003, 8555-8560.
http://dx.doi.org/10.1021/ja034447u

7."High Pressure IR Studies on the Asymmetric Hydroformylation of Styrene Catalyzed by Rh(I)–(R,S)-BINAPHOS'es"
Nozaki, K.; Matsuo, T.; Shibahara, F.; Hiyama, T. Organometallics 2003, 22, 594-600.
http://dx.doi.org/10.1021/om020245f

6."Asymmetric Hydroformylation with Highly Crosslinked Polystyrene-supported (R,S)-BINAPHOS–Rh(I) Complexes: the Effect of Immobilization Position"
Shibahara, F.
; Nozaki, K.; Matsuo, T.; Hiyama, T. Bioorg. Med. Chem. Lett. 2002, 12, 1825-1827.
http://dx.doi.org/10.1016/S0960-894X(02)00267-6

5."Alternating Copolymerization of w-Perfluoroalkyl-1-alkenes with Carbon Monoxide Catalyzed by Homogeneous and Polymer-supported Pd-complexes"
Nozaki, K.; Shibahara, F.; Elzner, S.; Hiyama, T. Can. J. Chem. 2001, 79, 593-597.
http://dx.doi.org/10.1139/cjc-79-5-6-593

4."Substituent Effect in Asymmetric Hydroformylation of Olefins Catalyzed by Rhodium(I) Complexes of (R,S)-BINAPHOS Derivatives: A Protocol for Improvement of Regio- and Enantioselectivities" Nozaki, K.; Matsuo, T.; Shibahara, F.; Hiyama, T. Adv. Synth. Catal. 2001, 343, 61-63.
http://dx.doi.org/10.1002/1615-4169(20010129)343:1<61::AID-ADSC61>3.0.CO;2-L

3."Vapor-phase Asymmetric Hydroformylation"
Nozaki, K; Shibahara, F.; Hiyama, T. Chem. Lett. 2000, 694-695.
http://dx.doi.org/10.1246/cl.2000.694

2."Asymmetric Hydroformylation of Olefins in Highly Cross-Linked Polymer Matrixes"
Nozaki, K; Shibahara, F.; Itoi, Y.; Shirakawa, E.; Ohta, T.; Takaya, H.; Hiyama, T. Bull. Chem. Soc. Jpn. 1999, 72, 1911-1918.
http://dx.doi.org/10.1246/bcsj.72.1911

1."Asymmetric Hydroformylation of Olefins in a Highly Cross-Linked Polymer Matrix"
Nozaki, K.; Itoi, Y.; Shibahara, F.; Shirakawa, E.; Ohta, T.; Takaya, H.; Hiyama, T. J. Am. Chem. Soc. 1998, 120, 4051-4052.
http://dx.doi.org/10.1021/ja973408d

Reviews and accouts

3. "Formation of C-C Bonds via Ruthenium Catalyzed Transfer Hydrogenation: Carbonyl Addition from the Alcohol or Aldehyde Oxidation Level"
Shibahara, F.
; Krische, M. J. Chem. Lett. 2008, 1102-1107.
http://dx.doi.org/10.1246/cl.2008.1102

2. "Efficient Synthetic Method for Novel Azaindolizines as Organic Light-Emitting Devices"
Murai, T.; Shibahara, F.Kagaku Kogyo 2008, 59, 686-691. (Written in Japanese)

‚P."Asymmetric Hydroformylation Catalyzed by Highly Cross-Linked Polystyrene-Supported (R,S)-BINAPHOS-Rh(I) Complexes"
Shibahara, F.
; Nozaki, K.; Hiyama, T. J. Synth. Org. Chem., Jpn. (Yuki Gosei Kagaku Kyokaishi) 2003, 61, 694-705.(Written in Japanese)

(updated in Apr. 9. 2009)

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