Publications & Presentations

 

Original Papers (since 2005)

2018

5. Synthesis of Chiral Selenazolines from N-Acyloxazolidinones via a Selenative Rearrangement of Chiral Cyclic Skeletons

Shibahara, F.; Fukunaga, T.; Kubota, S.; Yoshida, A.; Murai, T.
Org. Lett. 2018, in press.

http://dx.doi.org/10.1021/acs.orglett.8b02520


4. Synthesis and Photophysical Properties of 5-N-Arylaminothiazoles with Sulfur-Containing Groups on the Aromatic Ring at the 2-Position

Murai, T.; Furukawa, H.; Yamaguchi, K.
Heterocycles 2018, in press. (Special Issues in Honor of Professor Kiyoshi Tomioka’s 70th Birthday)

http://dx.doi.org/10.3987/COM-18-S(T)28


3. Chelation‐Assisted β‐Selective Direct C−H Bond Arylation of 2‐Thienylthioamide Catalyzed by Palladium–1,10‐Phenanthroline Complexes

Shibahara, F.; Asai, Y.; Murai, T.

Asian J. Org. Chem. 2018, 7(7), 1323-1326. (in Special Issue on C-H Activation)

(Selected as a Very Important Paper and Cover Feature)

http://dx.doi.org/10.1002/ajoc.201800160
Cover Feature: https://doi.org/10.1002/ajoc.201800206

Highlighted in ChemistryViews


2. Selenolactams as Synthetic Intermediates for the Synthesis of Polycyclic Amines via Seleno-Claisen Rearrangements

Shibahara, F.; Suzuki, M.; Kubota, S.; Fukunaga, T.; Udagawa, T.; Murai, T.

J. Org. Chem. 2018, 83 (6), 3078-3089. (Selected as a Featured Articles)

http://dx.doi.org/10.1021/acs.joc.8b00306


1. Hydrolysis of Phosphonothioates with a Binaphthyl Group: P-Stereogenic O-Binaphthyl Phosphonothioic Acids and Their Use as Optically Active Ligands and Chiral Discriminating Agents

Kuwabara, K.; Maekawa, Y.; Minoura, M.; Murai, T.

Org. Lett. 2018, 20 (5), 1375-1379.

http://dx.doi.org/10.1021/acs.orglett.8b00147


2017

7. Pyridinium 5-aminothiazoles: specific photophysical properties and vapochromism in halogenated solvents

Yamaguchi, K.; Murai, T.; Tsuchiya, Y.; Miwa, Y.; Kutsumizu, S.; Sasamori, T.; Tokitoh, N.

RSC Adv. 2017, 7 (29), 18132-18135.

http://dx.doi.org/10.1039/C7RA01896G


6. Employing BINOL-Phosphoroselenoyl Chloride for Selective Inositol Phosphorylation and Synthesis of Glycosyl Inositol Phospholipid from Entamoeba histolytica

Aiba, T.; Suehara, S.; Choy, S.-L.; Maekawa, Y.; Lotter, H.; Murai, T.; Inuki, S.; Fukase, K.; Fujimoto, Y.

Chem. Eur. J. 2017, 23 (34), 8304-8308.

http://dx.doi.org/10.1002/chem.201701298


5. Synthesis of P-stereogenic phosphinates via an axis-to-center chirality transfer by the reaction of phosphonates having a binaphthyloxy group with Grignard reagents

Maekawa, Y.; Kuwabara, K.; Sugiyama, A.; Iwata, K.; Maruyama, T.; Murai, T.

Chem. Lett. 2017, 46 (8), 1077-1079. (Selected as an Editor’s Choice)

http://dx.doi.org/10.1246/cl.170395


4. Synthesis and Photophysical Properties of 5-N-Arylamino-4-methylthiazoles Obtained from Direct C-H Arylations and Buchwald-Hartwig Aminations of 4-Methylthiazole

Murai, T.; Yamaguchi, K.; Hayano, T.; Maruyama, T.; Kawai, K.; Kawakami, H.; Yashita, A.

Organometallics 2017, 36 (14), 2552-2558.

http://dx.doi.org/10.1021/acs.organomet.7b00128


3. The first selenium isologues of 2-pyrones and coumarins: Synthesis, structures, and reactions

Murai, T.; Yoshida, A.; Mizutani, T.; Kubuki, H.; Yamaguchi, K.; Maruyama, T.; Shibahara, F.
Chem. Lett. 2017, 46 (7), 1017-1019.
http://dx.doi.org/10.1246/cl.170341


2. Experimental and Theoretical Examination of the Radical Cations Obtained from the Chemical and Electrochemical Oxidation of 5-Aminothiazoles

Yamaguchi, K.; Murai, T.; Kutsumizu, S.; Miwa, Y.; Ebihara, M.; Guo, J.-D.; Tokitoh, N.

ChemistryOpen 2017, 6 (2), 282-287.

http://dx.doi.org/10.1002/open.201700016


1. Imidazo[1,5-a]pyridin-3-ylidenes as π-accepting carbene ligands: substituent effects on properties of N-heterocyclic carbenes

Koto, Y.; Shibahara, F.; Murai, T.

Org. Biomol. Chem. 2017, 15, 1810-1820.

http://dx.doi.org/10.1039/C6OB02827F


2016

6. Sequential Deprotonation-Alkylation of Binaphthyloxy-Substituted Phosphonochalcogenoates: Chiral Tri- and Tetrasubstituted Carbon Centers Adjacent to a Phosphorus Atom

Maekawa, Y.; Maruyama, T.; Murai, T.

Org. Lett. 2016, 18(20), 5264-5267.

http://dx.doi.org/10.1021/acs.orglett.6b02578


5. Sequential Addition Reaction of Sulfanylmethyllithiums and Grignard Reagents to Thioformamides Leading to the Formation of 2-Phenyl-2-sulfanylethyl Tertiary Amines

Murai, T.; Mutoh, N.

J. Org. Chem. 2016, 81(18), 8131-8134.

http://dx.doi.org/10.1021/acs.joc.6b01857


4. 1-Substituted-imidazo[1,5-a]pyridin-3-ylidenes as Highly Efficient Ligands for Rh- and Ir-catalyzed Transfer Hydrogenation of Carbonyl Compounds

Koto, Y.; Shibahara, F.; Murai, T.

Chem. Lett. 2016, 45, 1327-1329.

http://dx.doi.org/10.1246/cl.160740


3. Acid-Responsive Absorption and Emission of 5-N- Arylaminothiazoles: Emission of White Light from a Single Fluorescent Dye and a Lewis Acid

Yamaguchi, K.; Murai, T.; Guo, J.-D.; Sasamori, T.; Tokitoh, N.

ChemistryOpen 2016, 5(5), 434-438.

http://dx.doi.org/10.1002/open.201600059


2. Phosphonoselenoic Acid Esters from the Reaction between Phosphoroselenoyl Chlorides and Grignard Reagents: Synthetic and Stereochemical Aspects

Murai, T.; Maekawa, Y.; Hirai, Y.; Kuwabara, K.; Minoura, M.

RSC Adv. 2016, 6, 15180-15183.

http://dx.doi.org/10.1039/c6ra00318d


1. Discrimination of Remote Chirality of Primary Alcohols Using 1,1'-Binaphthyl-2,2'-diyl Phosphoroselenoyl Chlorides as a Chiral Molecular Tool

Murai, T.; Itoh, H.

Phosphorus, Sulfur, and Silicon 2016, 191(2), 163-173.

http://dx.doi.org/10.1080/10426507.2015.1085050


2015

4. Direct C−H Bond Arylation of Thienyl Thioamides Catalyzed by Pd−Phenanthroline Complexes

Yamauchi, T.; Shinbahara, F.; Murai, T.

Org. Lett. 2015, 17(21), 5392-5395.

http://dx.doi.org/10.1021/acs.orglett.5b02742


3. 5‐N-Arylaminothiazoles as Highly Twisted Fluorescent Monocyclic Heterocycles: Synthesis and Characterization

Yamaguchi, K.; Murai, T.; Hasegawa, S.; Miwa, S.; Kutsumizu, S.; Maruyama, T.; Sasamori, T.; Tokitoh, N.

J. Org. Chem. 2015, 80(13), 10742-10756.

http://dx.doi.org/10.1021/acs.joc.5b01963


2. α–Hydroxy and α–Oxo Selenoamides: Synthesis via Nucleophilic Selenocarbamoylation of Carbonyl Compounds and Characterization

Murai, T.; Mizutani, T.; Ebihara, M.; Maruyama, T.

J. Org. Chem. 2015, 80(13), 6903-6907.

http://dx.doi.org/10.1021/acs.joc.5b00969


1. Rhodium(I) and Iridium(I) Imidazo[1,5-a]pyridine-1-ylalkylalkoxy Complexes: Synthesis, Characterization and Application as Catalysts for Hydrosilylation of Alkynes

Murai, T.; Nagaya, E.; Shibahara, F.; Maruyama, T.; Nakazawa, H.

J. Organomet. Chem. 2015, 794, 76–80.

http://dx.doi.org/10.1016/j.jorganchem.2015.05.045


2014

7. Fluorinative Hydrolysis of Phosphorothioic Acid Esters with a Binaphthyl Group Through Axis-to-Center Chirality Transfer Leading to the Formation of P-Chiral Phosphorothioic Monofluoridic Acid Salts

Murai, T.; Hayashi, T.; Yamada, K.; Maekawa, Y. Minoura M.

Chem. Commun. 2014 12473-12475.

http://dx.doi.org/10.1039/c4cc05198j


6. Transformation of RN=CHPh to R(R’3Si)NCH2Ph in the Catalytic Desulfurization of Secondary Thioamide with R’3SiH Promoted by an Iron Complex

Fukumoto, K.; Sakai, A.; Murai, T.; Nakazawa, H.

Heteroatom Chem. 2014, 25(6), 607-6011.

http://dx.doi.org/10.1002/hc.21175


5. Kinetic Resolution of Secondary 2-Aryl-1-cycloalkanols with Phosphoroselenoyl Chloride with a Binaphthyl Group

Murai. T.; Miwa, T.

Heteroatom Chem. 2014, 25(5), 337-347.

http://dx.doi.org/10.1002/hc.21168


4. Facile Synthetic Method for Diverse Polyfunctionalized Imidazoles by Means of Pd-Catalyzed C–H Bond Arylation of N-Methyl-4,5-dibromoimidazole

Yamauchi, T.; Shibahara, F.; Murai, T.

J. Org. Chem. 2014, 79(15), 7185-7192.

http://dx.doi.org/10.1021/jo5013493


3. Aromatic Selenoic, Selenothioic, and Diselenoic Acid Salts: Isolation, Characterization, and Se-77 NMR Spectra, Together with Theoretical Elucidation

Murai, T.; Nishi, D.; Hayashi, S.; Nakanishi, W.

Bull. Chem. Soc. Jpn. 2014, 87(6), 677-692. (Selected Papers)

http://dx.doi.org/10.1246/bcsj.20140018


2. Reaction of Selenoamide Dianions with Thio- and Selenoformamides Leading to the Formation of 5-Aminoselenazoles: Photophysical and Electrochemical Properties

Murai, T.; Yamaguchi, K.; Hori, F.; Maruyama, T.

J. Org. Chem. 2014, 79(11), 4930- 4939.

http://dx.doi.org/10.1021/jo500499g


1. Copper-Catalyzed C-H Bond Direct Chalcogenation of Aromatic Compounds Leading to Diaryl Sulfides, Selenides, and Diselenides by Using Elemental Sulfur and Selenium as Chalcogen Sources Under Oxidative Conditions

Shibahara, F.; Kanai, T.; Yamaguchi, E.: Kamei, A.; Yamauchi, T.; Murai, T.

Chem. –Asian. J. 2014, 9(1), 237-244.

http://dx.doi.org/10.1002/asia.201300882


2013

4. Sequential One-Pot Addition of Excess Aryl-Grignard Reagents and Electrophiles to O-Alkyl Thioformates

Murai, T.; Morikawa, K.; Maruyama, T.

Chem. –Eur. J. 2013, 19(39), 13112-13119.

http://dx.doi.org/10.1002/chem.201301573


3. Anti-Markovnikov Hydrophosphoroselenoylation of Alkenes Using Phosphorodiselenoic Acid Esters Leading to the Formation of Phosphonoselenoic Acid Esters

Murai, T.; Maekawa, Y.; Monzaki, M.; Ando, T.; Maruyama, T.

Chem. Commun. 2013, 49(83), 9675-9677.

http://dx.doi.org/10.1039/C3CC45912H


2. Synthesis and Characterization of Boron Complexes of Imidazo[1,5-a]pyridylalkylalcohols

Murai, T.; Nagaya, E.; Miyahara, K.; Maruyama, T.; Shibahara, F.

Chem. Lett. 2013, 42(8), 828-830.

http://dx.doi.org/10.1246/cl.130274


1. Diastereo- and Regioselective Addition of Thioamide Dianions to Imines and Aziridines: Syntheses of N-Thioacyl 1,2-, and 1,3-Diamines

Shibahara, F.; Kobayashi, S.; Maruyama, T.; Murai, T.

Chem. –Eur. J. 2013, 19(1), 304-313.

http://dx.doi.org/10.1002/chem.201203470


2012

5. One-pot Sequential Direct C-H Bond Arylation of Azoles Catalyzed by [Pd(phen)2](PF6)2

Shibahara, F.; Yamauchi, T.; Yamaguchi, E.; Murai, T.

J. Org. Chem. 2012, 77(19), 8815-8820.

http://dx.doi.org/10.1021/jo301621t


4. Synthesis of γ,δ-Unsaturated Selenoamides via the Seleno-Claisen Rearrangement of in situ Generated Allylic Vinyl Selenides from Selenoamides and Allylic Bromides

Murai. T.; Ezaka, T.; Kato S.

Synthesis 2012, 44(20), 3197-3201.

http://dx.doi.org/10.1055/s-0032-1317149


  1. 3.Generation and characterization of aliphatic selenothioic acid salts

Murai, T.; Nonoyama, T.

Tetrahedron 2012, 68(51), 10489-10495.

http://dx.doi.org/10.1016/j.tet.2012.06.076


2. Palladium-catalyzed C-H bond direct alkynylation of 5-membered heteroarenes: A well-defined synthetic route to azole derivatives containing two different alkynyl groups

Shibahara, F.; Dohke, Y.; Murai, T.

J. Org. Chem. 2012, 77(12), 5381-5388.

http://dx.doi.org/10.1021/jo3008385


1. Imidazo[1,5-a]pyridine-1-ylalkylalcohols: synthesis via intramolecular cyclization of N-thioacyl 1,2-aminoalcohols and their silyl ethers and molecular structures

Murai, T.; Nagaya, E.; Shibahara, F.; Maruyama, T.

Org. Biomol. Chem. 2012, 10(25), 4943-4953.

http://dx.doi.org/10.1039/C2OB25438G


2011

  1. 6.Sequential One-Pot Reaction of Thioformamide with Organolithium and Zinc Reagents

Murai. T,; Matsushita, K.

Phosphorus, Sulfur Silicon Relat. Elem. 2011, 186(5), 1094-1103.

http://dx.doi.org/10.1080/10426507.2010.520289


5. 1-Alkynyl- and 1-Alkenyl-3-arylimidazo[1,5-a]pyridines: Synthesis, Photophysical Properties, and Observation of a Linear Correlation Between the Fluorescent Wavelength and Hammett Substituent Constants

Yamaguchi, E.; Shibahara, F.; Murai, T.

J. Org. Chem. 2011, 76(15), 6146-6158.

http://dx.doi.org/10.1021/jo200864x


4. Direct Sequential C3 and C1 Arylation Reaction of Imidazo[1,5-a]pyridine Catalyzed by a 1,10-Phenanthroline Palladium Complex

Yamaguchi, E.; Shibahara, F.; Murai, T.

Chem. Lett. 2011, 40(9), 939-940.
http://dx.doi.org/10.1246/cl.2011.939


3. Direct Arylation of Simple Azoles Catalyzed by 1,10-Phenanthroline Containing Palladium Complexes: An Investigation of C4 Arylation of Azoles and the Synthesis of Triarylated Azoles by Sequential Arylation

Shibahara, F.; Yamaguchi, E.; Murai, T.

J. Org. Chem. 2011, 76(8), 2680-2693.

http://dx.doi.org/10.1021/jo200067y


2. Intramolecular Cyclization of in Situ Generated Adducts Formed between Thioamide Dianions and Thioformamides Leading to Generation of 5-Amino-2-thiazolines and 5-Aminothiazoles, and Their Fluorescence Properties

Murai, T.; Hori, F.; Maruyama, T.

Org. Lett. 2011, 13(7), 1718-1721.

http://dx.doi.org/10.1021/ol200231z


1. Sequential one-pot reactions of thioformates with lithium silylacetylides, arylmagnesium halides, and electrophiles leading to formation of propargyl sulfides

Murai, T.; Ohashi, T.; Shibahara, F.

Chem. Lett. 2011, 40(1), 70-71. (Editors Choice)

http://dx.doi.org/10.1246/cl.2011.70


2010

5. (Selenocarbamoyl)silanes and -germanes: Their Synthesis Using (Selenocarbamoyl)lithium and Characterization

Murai, T.; Hori, R.; Maruyama, T.; Shibahara, F.

Organometallics 2010, 29(11), 2400-2402.

http://dx.doi.org/10.1021/om100290h


4. Assignment of the absolute configurations of 1-aryl-2-propanols with the use of phosphoroselenoyl chlorides as chiral derivatizing agents

Murai, T.; Tsuji, H.; Imaizumi, S.; Maruyama, T.

Chem. Lett. 2010, 39(5), 524-526.

http://dx.doi.org/10.1246/cl.2010.524


3. Direct multiple C-H bond arylation reaction of heteroarenes catalyzed by cationic palladium complex bearing 1,10-phenanthroline

Shibahara, F.; Yamaguchi, E.; Murai, T.

Chem. Commun. 2010, 46(14), 2471-2473.

http://dx.doi.org/10.1039/b920794e


2. Synthesis and properties of phosphoroselenoic acids and their salts bearing binaphthyl groups

Murai, T.; Monzaki, M.; Katoh, T.; Suzuki, T.; Akiyama, T.

Phosphorus, Sulfur Silicon Relat. Elem. 2010, 185(5-6), 964-973.

http://dx.doi.org/10.1080/10426501003771575


1. Synthesis and properties of secondary thiocarbamoylsilanes

Murai, T.; Hori, R.

Bull. Chem. Soc. Jpn. 2010, 83(1), 52-57.

http://dx.doi.org/10.1246/bcsj.20090231


2009

9. Direct Thionation and Selenation of Amides Using Elemental Sulfur and Selenium and Hydrochlorosilanes in the Presence of Amines

Shibahara, F.; Sugiura, R.; Murai, T.

Org. Lett. 2009, 11(14), 3064-3067.

http://dx.doi.org/10.1021/ol9010882


8. Iodine-mediated cyclization of N-thioacyl-1-(2-pyridyl)-1,2-amino alcohols and their subsequent condensation leading to the formation of novel bis(1-imidazo[1,5-a]pyridyl)arylmethanes

Tahara, S.; Shibahara, F.; Maruyama, T.; Murai, T.

Chem. Commun. 2009, 7009-7011.

http://dx.doi.org/10.1039/b910172a


7. Phosphorofluoridic acid-catalyzed condensation reaction of carboxylic acids with 1-arylalkyl alcohols leading to esters under solvent-free conditions

Murai, T.; Tanaka, N.; Higashijima, S.; Miura, H.

Chem. Lett. 2009, 38(7), 668-669.

http://dx.doi.org/10.1246/cl.2009.668


6. Sequential Addition Reactions of Two Molecules of Grignard Reagents to Thioformamides

Murai, T.; Ui, K.; Narengerile

J. Org. Chem. 2009, 74(15), 5703-5706.

http://dx.doi.org/10.1021/jo900915n


5. Silylation and alkylation of thioamide dianions of N-arylmethyl secondary thioamides, and reduction of the resulting thioamides leading to secondary and primary amines

Murai, T.; Michigami, T.; Yamaguchi, M.; Mizuhata, N.

J. Sulfur Chem. 2009, 30(3-4), 225-235.

http://dx.doi.org/10.1080/17415990902774202


4. Syntheses and fluoride-ion-mediated hydrolysis of phosphoroselenoic acid ester and amides

Murai, T.; Inaji, S.; Takenaka, T.

Heteroat. Chem. 2009, 20(5), 255-261.

http://dx.doi.org/10.1002/hc.20544


3. Syntheses and stability of alkynyl S,N-acetals derived from 2-propynals

Murai, T; Fukushima, K.; Ohta, Y.; Mutoh, Y.

Phosphorus, Sulfur Silicon Relat. Elem. 2009, 184(6), 1462-1480.

http://dx.doi.org/10.1080/10426500902947765


2. Synthesis of 1,3-diarylated imidazo[1,5-a]pyridines with a combinatorial approach: metal-catalyzed cross-coupling reactions of 1-halo-3-arylimidazo[1,5-a]pyridines with arylmetal reagents

Shibahara, F.; Yamaguchi, E.; Kitagawa, A.; Imai, A.; Murai, T.

Tetrahedron 2009, 65(26), 5062-5073. (Symposium-in-print No. 42, Recent Advances in Catalysis and Green Chemistry)

http://dx.doi.org/10.1016/j.tet.2009.02.062


1. Synthesis of fluorescent 1,3-diarylated imidazo[1,5-a]pyridines: Oxidative condensation-cyclization of aryl-2-pyridylmethylamines and aldehydes with elemental sulfur as an oxidant

Shibahara, F.; Sugiura, R.; Yamaguchi, E.; Kitagawa, A.; Murai, T.

J. Org. Chem. 2009, 74(9), 3566-3568.

http://dx.doi.org/10.1021/jo900415y


2008

3. Copper-catalyzed oxidative desulfurization-promoted intramolecular cyclization of thioamides using molecular oxygen as an oxidant: an efficient route to five- to seven-membered nitrogen-containing heterocycles

Shibahara, F.; Yoshida, A.; Murai, T.

Chem. Lett. 2008, 37(6), 646-647.

http://dx.doi.org/10.1246/cl.2008.646


2. Diastereoselective Synthesis of N-Secondary Alkyl 2-Alkoxymethylpyrrolidines via Sequential Addition Reactions of Organolithium and -Magnesium Reagents to N-Thioformyl 2-Alkoxymethylpyrrolidines

Murai, T.; Asai, F.

J. Org. Chem. 2008, 73(23), 9518-9521.

http://dx.doi.org/10.1021/jo8021956


1. Fluoride-ion-mediated hydrolysis of phosphoric acid esters, amides, and phosphorous acid esters leading to phosphorofluoridic, phosphoramide fluoridic, and phosphonic acid monoester salts

Murai, T.; Takenaka, T.; Inaji, S.; Tonomura, Y.

Chem. Lett. 2008, 37(12), 1198-1199.

http://dx.doi.org/10.1246/cl.2008.1198


2007

6. Copper-catalyzed oxidative desulfurization-oxygenation of thiocarbonyl compounds using molecular oxygen: an efficient method for the preparation of oxygen isotopically labeled carbonyl compounds

Shibahara, F.; Suenami, A.; Yoshida, A.; Murai, T.

Chem. Commun. 2007, 2354-2356.

http://dx.doi.org/10.1039/b701048f


5. Sequential addition reactions of lithium acetylides and grignard reagents to selenoiminium salts leading to 2-propynyl tertiary amines bearing a tetrasubstituted carbon center

Murai, T.; Nogawa, S.; Mutoh, Y.

Bull. Chem. Soc. Jpn. 2007, 80(11), 2220-2225.

http://dx.doi.org/10.1246/bcsj.80.2220


4. Synthesis and Properties of [1-(Methylthio)propargyl]ammonium Salts and Their Use as Key Precursors to Sulfur-Containing Enediynes

Murai, T.; Fukushima, K.; Mutoh, Y.

Org. Lett. 2007, 9(25), 5295-5298.

http://dx.doi.org/10.1021/ol7024923


3. Synthesis of 1,1'-binaphthyl-2,2'-diyl phosphoroselenoic ammonium salts and their conversion to optically active dialkyl diselenides

Murai, T.; Monzaki, M.; Shibahara, F.

Chem. Lett. 2007, 36(7), 852-853.

http://dx.doi.org/10.1246/cl.2007.852


2. Telluration of seleno- and chloroiminium salts leading to various telluroamides, and their structure and NMR properties

Mutoh, Y.; Murai, T.; Yamago, S.

J. Organomet. Chem. 2007, 692(1-3), 129-135.

http://dx.doi.org/10.1016/j.jorganchem.2006.03.045


1. Three-Component Coupling Reactions of Thioformamides with Organolithium and Grignard Reagents Leading to Formation of Tertiary Amines and a Thiolating Agent

Murai, T.; Asai, F.

J. Am. Chem. Soc. 2007, 129(4), 780-781.

http://dx.doi.org/10.1021/ja068523f


2006

5. 1,1'-Binaphthyl-2,2'-diyl Phosphoroselenoyl Chloride as a Chiral Molecular Tool for the Preparation of Enantiomerically Pure Alcohols and Amines

Murai, T.; Matsuoka, D.; Morishita, K.

J. Am. Chem. Soc. 2006, 128(14), 4584-4585.

http://dx.doi.org/10.1021/ja060308b


4. Sequential addition reaction of lithium acetylides and Grignard reagents to thioiminium salts from thiolactams leading to 2,2-disubstituted cyclic amines

Murai, T.; Toshio, R.; Mutoh, Y.

Tetrahedron 2006, 62(26), 6312-6320.

http://dx.doi.org/10.1016/j.tet.2006.04.065


3. Substituent effects on [1,3]-rearrangement of alkynyl S,N-acetals to 1-amino-3-sulfenylallenes and their conversion to a,b-unsaturated ketones

Murai, T.; Mutoh, Y.; Fukushima, K.

Lett. Org. Chem. 2006, 3(5), 409-413.

http://dx.doi.org/10.2174/157017806776611872


2. Synthesis of 1,1'-binaphthyl-2,2'-diyl phosphoroselenoic amides and their conversion to optically pure phosphoramidites

Murai, T.; Inaji, S.; Morishita, K.; Shibahara, F.; Tokunaga, M.; Obora, Y.; Tsuji, Y.

Chem. Lett. 2006, 35(12), 1424-1425.

http://dx.doi.org/10.1246/cl.2006.1424


1. Synthesis of 2-Azaindolizines by Using an Iodine-Mediated Oxidative Desulfurization Promoted Cyclization of N-2-Pyridylmethyl Thioamides and an Investigation of Their Photophysical Properties

Shibahara, F.; Kitagawa, A.; Yamaguchi, E.; Murai, T.

Org. Lett. 2006, 8(24), 5621-5624.

http://dx.doi.org/10.1021/ol0623623


2005

7. Addition reaction of zinc acetylides to thioiminium salts leading to 3-amino-1-sulfanyl-1,4-enynes

Murai, T.; Ohta, Y.; Mutoh, Y.

Tetrahedron Lett. 2005, 46(21), 3637-3640.

http://dx.doi.org/10.1016/j.tetlet.2005.03.166


6. Enantiomerically pure P-chiral phosphinoselenoic chlorides: inversion of configuration at the P-chirogenic center in the synthesis and reaction of these substances

Kimura, T.; Murai, T.

Chem. Commun. 2005, 4077-4079.

http://dx.doi.org/10.1039/b507755a


5. N-Thioacyl 1,3-Amino Alcohols: Synthesis via Ring-Opening of Oxiranes with Thioamide Dianions and Applications as Key Intermediates Leading to Stereochemically Defined 5,6-Dihydro-4H-1,3-oxazines and 1,3-Amino Alcohols

Murai, T.; Sano, H.; Kawai, H.; Aso, H.; Shibahara, F.

J. Org. Chem. 2005, 70(20), 8148-8153.

http://dx.doi.org/10.1021/jo051378o


4. Optically active P-chiral phosphinoselenoic amides: stereochemical outcome at the P-stereogenic center in the synthesis of these substances and their characterization

Kimura, T.; Murai, T.

Tetrahedron: Asymmetry 2005, 16(22), 3703-3710.

http://dx.doi.org/10.1016/j.tetasy.2005.09.028


3. P-Chiral Phosphinoselenoic Chlorides and Phosphinochalcogenoselenoic Acid Esters: Synthesis, Characterization, and Conformational Studies

Kimura, T.; Murai, T.

J. Org. Chem. 2005, 70(3), 952-959.

http://dx.doi.org/10.1021/jo0484979


2. Phosphinoselenothioic acids and their salts: synthesis, characterization, and reaction with electrophiles

Kimura, T.; Murai, T.; Miwa, A.; Kurachi, D.; Yoshikawa, H.; Kato, S.

J. Org. Chem. 2005, 70(14), 5611-5617.

http://dx.doi.org/10.1021/jo050576c


1. Selenophilic reaction of organolithium and magnesium reagents with phosphinoselenoic chlorides

Kimura, T.; Murai, T.; Mizuhata, N.

Heteroat. Chem. 2005, 16(3), 185-191.

http://dx.doi.org/10.1002/hc.20091



Reviews, Accounts and Book Chapters (since 2005)

2013

  1. 1.Direct C-H Bond Arylations of Heteroarenes Catalyzed by Palladium/Nitrogen-Based Ligand Complexes

Shibahara, F.; Murai, T.

Asian J. Org. Chem. 2013, 2(8), 624-636.

http://dx.doi.org/10.1002/ajoc.201300018


2012

2. Selenocarbonyls

Murai, T.

in Organoselenium Chemistry: Synthesis and Reactions, ed. by T. Wirth, Wiley-VCH, Weinheim, 2012, pp. 257–285.

http://dx.doi.org/10.1002/9783527641949.ch6


1. Thioamides and Thioformamides for Sequential Reactions with Organolithium and Grignard Reagents

Murai, T.; Mutoh, Y.

Chem. Lett. 2012, 41(1), 2-8.

http://dx.doi.org/10.1246/cl.2012.2


2011

1. Development of organic reactions by means of oxidative or reductive activation of sulfur atom

硫黄原子の酸化的・還元的活性化を経る有機合成反応の開発

Shibahara, F.; Murai, T.

有機合成化学協会誌 2011, 69(1), 28-37.

http://dx.doi.org/10.5059/yukigoseikyokaishi.69.28


2010

1. Thioamide dianions derived from N-arylmethyl thioamides: generation and application as carbon nucleophiles adjacent to the nitrogen atom

Murai, T.

Pure Appl. Chem. 2010, 82(3), 541-554.

http://dx.doi.org/10.1351/PAC-CON-09-08-04


2009

  1. 1.有機EL材料探索–含窒素10π電子系”アザインドリジン類”の電子材料への展開–

Shibahara, F.; Murai, T.

月刊ディスプレイ 2009, (9), 32-38.


2008

2.  Efficient Synthetic Method for Novel Azaindolizines as Organic Light-Emitting Devices

新規なアザインドリジン系有機EL用化合物の効率的な合成法

Murai, T.; Shibahara, F.

化学工業 2008, 59, 686-691.


1. Phosphoroselenoic Acid Derivatives Bearing a Binaphthyl Group as a Chiral Molecular Tool

Murai, T.

Phosphorus Sulfur Silicon Relat. Elem. 2008, 183(4), 889-896.

http://dx.doi.org/10.1080/10426500801898218


2006

1. Syntheses and properties of phosphinoselenoic chlorides, acids, and their salts

Murai, T.; Kimura, T.

Curr. Org. Chem. 2006, 10(15), 1963-1973.

http://dx.doi.org/10.2174/138527206778521231


2005

3. Chalcogenoiminium salts: Systematic synthesis and applications to carbon-carbon bond forming reactions

カルコゲノイミニウム塩:系統的合成と炭素-炭素結合形成反応への応用

Mutoh, Y.; Murai, T.

有機合成化学協会誌 2005, 63(8), 815-824.

http://dx.doi.org/10.5059/yukigoseikyokaishi.63.815


2. Synthesis and reactions of selenothioic acid S-esters and diselenoic acid esters

Murai, T.

Synlett 2005, 1509-1520.

http://dx.doi.org/10.1055/s-2005-869847


1. Thio-, seleno-, telluro-amides

Murai, T.

Top. Curr. Chem. 2005, 251(Chalcogenocarboxylic Acid Derivatives), 247-272.

http://dx.doi.org/10.1007/b101011